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Ice in the Galactic Center

Ash Barnes, Cara Battersby Alyssa Bulatek, Savannah Gramze, Jonny Henshaw, Desmond Jeff, Xing "Walker" Lu, Betsy Mills, Dan Walker, Brandt Gaches, Matt Ashby
Supported by the NSF: 2008101, 2206511, CAREER 2142300, STSCI grants 1905, 2221
Slides available at https://keflavich.github.io/talks/gc_ice_2025.html or from my webpage →talks
The role of ice in the ISM
Enemy:
Friend:
  • Nice molecules like CO freeze out
  • They make extinction curves weird
  • Grow grains, making dust harder to model
  • Delivers water and other good stuff to planets
  • Ices facilitate chemistry, making good stuff like CH2CH3OH
  • Can be used to measure metallicity?
The CMZ is one extreme of star forming conditions in the Galaxy
PPVII review: Henshaw, Barnes, Battersby, Ginsburg, Sormani, Walker
The Brick isn't forming many stars
despite a total mass ~105 M in <3 pc
Walker+ 2021
The Brick is icy
F466N F405N
The Brick is icy
F466N F405N
1-2 mag excess extinction (A4.66μm) at AV~60-90
CO gas has a limited effect

10% abs. = 0.1 mag
90% abs. = 2.5 mag

Gas absorption is limited to < 0.2 mag

Observed absorption goes to at least 2 mag (though lower limits go higher still)
The haze is recombintion line emission.
Blue is Pfβ & Huε, absorbed.
F466N F405N
Effect of CO (& CO2) ice & gas on JWST filters
Flat-spectrum background stars get blued in these filters
YSOs do not! They have rising spectra at 4 microns
Color-Color Diagram
≈ A$_V$
≈ N(CO)
F466N: CO, XCN, H$_2$O
F405N: Weak absorption
Colors constrain ice mixtures
Smith+ 2025:
Local clouds ~ 3:1:1
H$_2$O:CO:CO$_2$
If we adopt those ice models, we can infer the CO ice column density
If we adopt those ice models, we can infer the CO ice column density
Lots of stars: they map a coherent structure

Stars are bluer (icier) toward the center
We're jumping to another cloud for a moment...
The Galactic Center Dust ridge is also icy...
... and has a foreground cloud in front
We measure ice via stellar absorption
There are clear environmental differences
  • Smith+ 2025: 27 data points
This is a clearly star-forming cloud, but only moderately so (it's an IRDC)
Column density maps - of H$_2$ and CO ice
Both CO column and abundance are rising with column density
Abundance is rising with column density
  • Smith+ 2025: 27 data points
Now for stranger things: F356W excess absorption
Now for stranger things: F356W excess absorption
is correlated with CO ice
Simple molecule ices don't match
So what is it?
Same structure as CO (left), but there's less in the outskirts
CO2 ice is also detectable
CO2 ice is also detectable

Models don't match if we assume N(CO$_2$) $\propto$ N(H$_2$)

Probably CO$_2$ ice is processing into other molecules

looking forward

We can do this in (a lot) of other clouds.
e.g., water ice in Sgr B2

looking forward

There is potential to measure metallicity directly from photometry.

SPHEREX can do this better for stars it can resolve.
A substantial history of papers on star formation and kinematics in the Brick...
(these are just the papers with G0.253 in the title)

Sgr B2 is!



Budaiev+ 2024
371 protostars
with envelope masses 1-200 M in <1000 au
Desmond Jeff+ 2024

Ten hot cores in Sgr B2 DS
outside the massive clusters
TG ~ 200-500 K
M ~ 200 - 2900 M
(proto-O-stars / clusters)
~5% of cores are hot cores
[P12 Alva Kinman has cataloged 100's more protostars]
Sgr B2 DS: More massive cores than the Disk
Desmond Jeff+ 2024

Hot Cores

Hot cores are chemically rich sites of high-mass star formation.
They are only found in the more distant disk & CMZ regions

Hot Cores

Hot cores are chemically rich sites of high-mass star formation.
They are only found in the more distant disk & CMZ regions

So is Cloud C


Savannah Gramze
Linear evolution along the 'dust ridge' is not likely

NGC 3551 (Sun+ 2024)
Dust Ridge
P08 Houghton E/F, Brick: No/low SF.
Sgr B2, Cloud C: high SF
The Brick has lower column density than star-forming Sgr B2
but higher than nearly any cloud in the Galactic plane
F200W F182M F115W
F212N F200W F182M
F356W F212N F200W
F410M F356W F212N
F444W F410M F356W
F466N F444W F410M
Icy stars are seen behind the outskirts
stars behind/within the center of the brick are too extincted to detect even at 4μm
Icy stars are seen behind the outskirts
Icy stars are seen behind the outskirts
stars behind/within the center of the brick are too extincted to detect even at 4μm
Icy stars are seen behind the outskirts
Gas emission pointed toward freezeout already
(e.g., Rathborne+ "Baked Alaska": a frozen interior)
N2H+ contours on CO 3-2
Tgas > Tdust. Gas is heated by CRs & turbulence
At high CRIR, CO fails as a coolant because
CO + He+ → C+ + O + He
But, The Brick is a really weak emitter in C+
CO is limited as a coolant, but because of freezeout, not (just) CRs
Has JWST revealed new star formation?
No, not yet.
Brα and Paα excess sources exist, but they're uniformly distributed - not likely to be associated with star formation. (P08 Rebecca Houghton - similar result)
Summary
  • The Brick is (nearly) protostarless
  • Ice forms very readily in the GC environment
  • Early freezeout, in addition to CRs, may limit gas cooling
The MUBLO
Broad-Line
Broad-Line (broader than the CMZ)
Weird chemistry (no SiO?!?)
Dusty
...and cold, using SO LTE model
No NIR counterpart
No counterparts!
Hypotheses & Data